WHAT IS PAINT?
Paint is any liquid, liquefiable, or mastic composition which, after application to a substrate in a thin layer, is converted to a solid film. It is most commonly used to protect, color or provide texture to objects.
In 2011, South African archeologists reported finding a 100,000 year old human-made ochre-based mixture which could have been used like paint. Cave paintings drawn with red or yellow ochre, hematite, manganese oxide, and charcoal may have been made by early Homo-sapiens as long as 40,000 years ago.
Ancient colored walls at Dendera, Egypt, which were exposed for years to the elements, still possess their brilliant color, as vivid as when they were painted about 2,000 years ago. The Egyptians mixed their colors with a gummy substance, and applied them separate from each other without any blending or mixture. They appeared to have used six colors: white, black, blue, red, yellow, and green. They first covered the area entirely with white then traced the design in black, leaving out the lights of the ground color. They used minium for red, and generally of a dark tinge.
Pliny mentions some painted ceilings in his day in the town of Ardea, which had been done prior to the foundation of Rome. He expresses great surprise and admiration at their freshness, after the lapse of so many centuries.
Paint was made with the yolk of eggs and therefore, the substance would harden and adhere to the surface it is applied to. Pigment was made from plants, sand, and different soils. Most paints used either oil or water as a base.
A still extant example of 17th century house oil painting is Ham House in Surrey, England, where a primer was used along with several undercoats and an elaborate decorative overcoat; the pigment and oil mixture would have been pounded into a paste with a mortar and pestle. The process was done by hand by the painter and exposed them to lead poisoning due to the white-lead powder.
In 1718, Marshall Smith invented a machine designed for the grinding of colours. Although it is not know precisely how it operated, it was a device that increased the efficiency of pigment grinding dramatically. Soon, a company called Emerton and Manby was advertising exceptionally low priced paints that had been ground with labour saving technology:
One Pound of Colour ground in a Horse-Mill will paint twelve Yards of Work, whereas Colour ground any other Way, will not do half that Quantity.
By the proper onset of the Industrial Revolution, paint was being ground in steam powered mills and an alternative to lead based pigments was found in a white derivative of zinc oxide. Interior house painting increasingly became the norm as the 19th century progressed, both for decorative reasons and because the paint was effective in preventing the walls rotting from damp. Linseed oil was also increasingly used as an inexpensive binder.
In 1866, Sherwin-Williams in the United States opened as a large paint-maker and invented a paint that could be used from the tin without preparation.
It was not until the stimulus of World War II created a shortage of linseed oil in the supply markets that artificial resins, or alkyds, were invented. Cheap and easy to make, they also held the colour well and lasted for a long time.
Binder, vehicle and resins
The binder, commonly called the vehicle, is the film-forming component of paint. It is the only component that must be present. Components listed below are included optionally, depending on the desired properties of the cured film.
The binder imparts adhesion and strongly influences such properties as gloss, durability, flexibility, and toughness.
Binders include synthetic or natural resins such as alkyds, acrylics, vinyl-acrylics, vinyl acetate/ethylene (VAE), polyurethanes, polyesters, melamine resins, epoxy, or oils. Binders can be categorized according to the mechanisms for drying or curing. Although drying may refer to evaporation of the solvent or thinner, it usually refers to oxidative cross-linking of the binders and is indistinguishable from curing. Some paints form by solvent evaporation only, but most rely on cross-linking processes.
Paints that dry by solvent evaporation and contain the solid binder dissolved in a solvent are known as lacquers. A solid film forms when the solvent evaporates, and because the film can re-dissolve in solvent, lacquers are unsuitable for applications where chemical resistance is important. Classic nitrocellulose lacquers fall into this category, as do non-grain raising stains composed of dyes dissolved in solvent and more modern acrylic-based coatings such as 5-ball Krylon aerosol. Performance varies by formulation, but lacquers generally tend to have better UV resistance and lower corrosion resistance than comparable systems that cure by polymerization or coalescence.
The paint type known as Emulsion is a water-borne dispersion of sub-micrometre polymer particles. These terms in their respective countries cover all paints that use synthetic polymers such as acrylic, vinyl acrylic (PVA), styrene acrylic, etc. as binders. Such paints cure by a process called coalescence where first the water, and then the trace, or coalescing, solvent, evaporate and draw together and soften the binder particles and fuse them together into irreversibly bound networked structures, so that the paint will not re-dissolve in the solvent/water that originally carried it. The residual surfactants in paint as well as hydrolytic effects with some polymers cause the paint to remain susceptible to softening and, over time, degradation by water. Paints that cure by oxidative crosslinking are generally single package coatings. When applied, the exposure to oxygen in the air starts a process that crosslinks and polymerizes the binder component. Classic alkyd enamels would fall into this category. Oxidative cure coatings are catalyzed by metal complex driers such as cobalt naphthenate.
There are paints called plastisols / organosols, which are made by blending PVC granules with a plasticizer. These are stoved and the mix coalesces. Other films are formed by cooling of the binder, for example, encaustic or wax paints are liquid when warm, and harden upon cooling. In many cases, they will re-soften or liquify if reheated.
Recent environmental requirements restrict the use of volatile organic compounds (VOCs), and alternative means of curing have been developed, particularly for industrial purposes. In UV curing paints, the solvent is evaporated first, and hardening is then initiated by ultraviolet light. In powder coatings there is little or no solvent, and flow and cure are produced by heating of the substrate after electrostatic application of the dry powder.
Diluent and Solvent
The main purposes of the diluent are to dissolve the polymer and adjust the viscosity of the paint. It is volatile and does not become part of the paint film. It also controls flow and application properties, and in some cases can affect the stability of the paint while in liquid state. Its main function is as the carrier for the non-volatile components. To spread heavier oils (for example, linseed) as in oil-based interior house paint, thinner oil is required. These volatile substances impart their properties temporarily—once the solvent has evaporated, the remaining paint is fixed to the surface.
Solvent-borne, also called oil-based, paints can have various combinations of organic solvents as the diluent, including aliphatics, aromatics, alcohols, ketones and white spirit. Specific examples are organic solvents such as petroleum distillate, esters, glycol ethers, and the like. Sometimes volatile low-molecular weight synthetic resins also serve as diluents.
Pigment and Filler
Pigments are granular solids incorporated in the paint to contribute color. Fillers are granular solids incorporate to impart toughness, texture, give the paint special properties, or to reduce the cost of the paint. Alternatively, some paints contain dyes instead of or in combination with pigments.
Pigments can be classified as either natural or synthetic. Natural pigments include various clays, calcium carbonate, mica, silica, and talc. Synthetics would include engineered molecules, calcined clays, blanc fixe, precipitated calcium carbonate, and synthetic pyrogenic silica’s.
Hiding pigments, in making paint opaque, also protect the substrate from the harmful effects of ultraviolet light. Hiding pigments include titanium dioxide, phthalo blue, red iron oxide, and many others.
Fillers are a special type of pigment that serves to thicken the film, support its structure and increase the volume of the paint. Fillers are usually cheap and inert materials, such as diatomaceous earth, talc, lime, barytes, clay, etc. Floor paints that will be subjected to abrasion may contain fine quartz sand as filler. Not all paints include fillers. On the other hand, some paints contain large proportions of pigment/filler and binder.
Some pigments are toxic, such as the lead pigments that are used in lead paint. Paint manufacturers began replacing white lead pigments with titanium white (titanium dioxide), before lead was banned in paint for residential use in 1978 by the US Consumer Product Safety Commission. The titanium dioxide used in most paints today is often coated with silica/alumina/zirconium for various reasons, such as better exterior durability, or better hiding performance (opacity) promoted by more optimal spacing within the paint film.
Besides the three main categories of ingredients, paint can have a wide variety of miscellaneous additives, which are usually added in small amounts, yet provide a significant effect on the product. Some examples include additives to modify surface tension, improve flow properties, improve the finished appearance, increase wet edge, improve pigment stability, impart anti-freeze properties, control foaming, control skinning, etc.
Other types of additives include catalysts, thickeners, stabilizers, emulsifiers, texturizers, adhesion promoters, UV stabilizers, flatteners (de-glossing agents), biocides to fight bacterial growth, and the like. Additives normally do not significantly alter the percentages of individual components in a formulation.
COLOR CHANGING PAINT
Various technologies exist for making paints that change color. Thermochromic paints and coatings contain materials that change conformation when heat is applied, and so they change color. Liquid crystals have been used in such paints, such as in the thermometer strips and tapes used in aquaria. Photochromic paints and coatings contain dyes that change conformation when the film is exposed to UV light, and so they change color. These materials are used to make eyeglasses.
Color changing paints can also be made by adding halochrome compounds or other organic pigments. One patent cites use of these indicators for wall coating applications for light colored paints. When the paint is wet it is pink in color but upon drying it regains its original white color. As cited in patent, this property of the paint enabled two or multiple coats to be applied on a wall properly and evenly. The previous coat/s having dried would be white whereas the new wet coat would be distinctly pink.
Electro-chromic paints change color in response to an applied electric current. A few companies have been reportedly working on electro-chromic paint, based on particles of paramagnetic iron oxide. When subjected to an electromagnetic field the paramagnetic particles change spacing, modifying their color and reflective properties. The electromagnetic field would be formed using the conductive metal of the car body. Electro-chromic paints can be applied to plastic substrates as well, using a different coating chemistry. The technology involves using special dyes that change conformation when an electric current is applied across the film itself. Recently, this new technology has been used to achieve glare protection at the touch of a button in passenger airplane windows.
Paint can be applied as a solid, a gaseous suspension (aerosol) or a liquid. Techniques vary depending on the practical or artistic results desired. As a solid (usually used in industrial and automotive applications), the paint is applied as a very fine powder, then baked at high temperature. This melts the powder and causes it to adhere to the surface. The reasons for doing this involve the chemistries of the paint, the surface itself, and perhaps even the chemistry of the substrate (the object being painted). This is called "powder coating" an object.
As a gas or as a gaseous suspension, the paint is suspended in solid or liquid form in a gas that is sprayed on an object. The paint sticks to the object. This is called "spray painting" an object. The reasons for doing this include:
- The application mechanism is air and thus no solid object touches the object being painted;
- The distribution of the paint is uniform, so there are no sharp lines;
- It is possible to deliver very small amounts of paint;
- A chemical (typically a solvent) can be sprayed along with the paint to dissolve together both the delivered paint and the chemicals on the surface of the object being painted;
- Some chemical reactions in paint involve the orientation of the paint molecules.
The application of the paint is fairly easily if done correctly. It is the prep work and order of operations that is tedious and detailed. Your first step when painting is to make sure you move all of the furniture, pictures, tables, etc. out of the room and most importantly out of your work space. Next is to lay down tarps or drop cloths to protect your flooring, but most of all if you spill or splash any paint. The next step, wall preparation, is a detailed process which could involve anything from skim coating, spackling, caulking, sanding, priming, taping, etc.
After all the prep work has been completed you can now begin painting. Usually your first step in painting should be the "cutting in phase". This phase includes the brushwork around the edges, windows, doors, trim, molding, ceiling or wall line, etc. It is up to the painter in which order of wall spaces he or she chooses to do first. For instance it does not matter if you cut into the ceiling or paint the window trim first and paint the walls last or vies versa. What is important is that the user cuts in first on every wall space. From there, depending of your order of operation, you can use a roller to roll-out the large open space on each wall space.
After you applied the necessary amount of coats to the wall, you can remove any tape left behind and clean up. It is recommended that you do not try to wash your walls for at least two weeks after painting to let the paint cure fully. In the liquid application, paint can be applied by direct application using brushes, paint rollers, blades, other instruments, or body parts such as fingers and thumbs.
Rollers generally have a handle that allows for different lengths of poles to be attached, allowing painting at different heights. Generally, roller application requires two coats for even color. A roller with a thicker nap is used to apply paint on uneven surfaces. Edges are often finished with an angled brush.
- Using the finish flat one would most likely use a 1/2" nap roller
- Using the finish eggshell one would most likely use a 3/8" nap roller
- Using the finish satin or pearl one would most likely use a 3/8" nap roller
- Using the finish semi-gloss or gloss one would most likely use a 3/16" nap roller
After liquid paint is applied, there is an interval during which it can be blended with additional painted regions (at the "wet edge") called "open time." The open time of an oil or alkyd-based emulsion paint can be extended by adding white spirit, similar glycols such as Dowanol (propylene glycol ether) or open time prolongers. This can also facilitate the mixing of different wet paint layers for aesthetic effect. Latex and acrylic emulsions require the use of drying retardants suitable for water-based coatings.
Spray paint application
Paint application by spray is the most popular method in many industries. In this, paint is atomized by the force of compressed air or by the action of high pressure compression of the paint itself, and the paint is turned into small droplets which travel to the article which is to be painted. Alternate methods are airless spray, hot spray, hot airless spray, and any of these with an electrostatic spray included. There are numerous electrostatic methods available.
Many paints tend to separate when stored, the heavier components settling to the bottom, and require mixing before use. Some paint outlets have machines for mixing the paint by shaking the can vigorously for a few minutes.
Water based paint
Water-based paints tend to be the easiest to clean up after use; the brushes and rollers can be cleaned with soap and water.
Disposal of paint
To dispose of paint it can be dried and disposed of in the domestic waste stream, provided that it contains no prohibited substances (see container). Disposal of liquid paint usually requires special handling and should be treated as hazardous waste, and disposed of according to local regulations.
Proper disposal of left over paint is a challenge. Sometimes it can be recycled: Old paint may be usable for a primer coat or an intermediate coat, and paints of similar chemistry can be mixed to make a larger amount of a uniform color.
Primer is a preparatory coating put on materials before painting. Priming ensures better adhesion of paint to the surface, increases paint durability, and provides additional protection for the material being painted. It can also be used to block and seal stains, or to hide a color that is to be painted over.
Emulsion paint is a water-based paint used for painting interior or exterior surfaces.
This finish is generally used on ceilings or walls that are in bad shape. This finish is more forgiving in terms of hiding imperfections in your walls and covers greatly. However this finish provides no washability if you were to get a stain on the wall.
This finish is very similar if not the same to the flat finish, but comes with some washability and good coverage.
This finish has some sheen to it, the equivalence to a shell on an egg. This finish provides great washability, but shows some imperfections on walls. This finish is ideal for bathrooms because it offers not only washability, but has enough shine so water will not stick to it and make it peel.
Pearl (Satin) Finish:
This is very durable in terms of washability and resistance to moisture. It will offer the user the full protection on their walls from dirt, moisture, stains, etc. This finish is ideal for bathrooms, furniture, and kitchens, but will show even more imperfections on walls because of its strong shine (this finish is shinier then eggshell).
This finish is typically used on trim to add detail, elegance, and to show off the wood work. It is used on doors and furniture as well. This is a very high shine, but provides the most protection from moisture and stains on your walls. Obviously this finish will show the imperfections on the wall tremendously. This finish is generally used where washability and durability are the only considerations.
Varnish provides a protective coating without changing the color. They are paints without pigment.
Wood stain is a type of paint that is very "thin," that is, low in viscosity, and formulated so that the pigment penetrates the surface rather than remaining in a film on the surface. Stain is predominantly pigment or dye and solvent with little binder, designed primarily to add color without providing a surface coating.
Lacquer is usually a fast-drying solvent-based paint or varnish that produces an especially hard, durable finish.
An enamel paint is a paint that dries to an especially hard, usually glossy, finish. Enamel paints sometimes contain glass powder or tiny metal flake fragments instead of the color pigments found in standard oil-based paints. Enamel paint is sometimes mixed with varnish or urethane to increase shine as well as assist its hardening process.
A glaze is an additive used with paint to slow drying time and increase translucency, as in faux painting and Art Painting.
A roof coating is a fluid applied membrane which has elastic properties that allows it to stretch and return to their original shape without damage. It provides UV protection to polyurethane foam and is widely used as part of a roof restoration system.
Anti-graffiti coatings are used to defeat the marking of surfaces by graffiti vandals. There are two categories, sacrificial and non-bonding. Sacrificial coatings are clear coatings that allow the removal of graffiti, usually by pressure washing the surface with high-pressure water, removing the graffiti, and the coating (hence, sacrificed). They must be re-applied afterward for continued protection. This is most commonly used on natural-looking masonry surfaces, such as statuary and marble walls, and on rougher surfaces that are difficult to clean. Non-bonding coatings are clear, high-performance coatings, usually catalyzed polyurethanes, that allow the graffiti very little to bond to. After the graffiti is discovered, it can be removed with the use of a solvent wash, without damaging the underlying substrate or protective coating. These work best when used on smoother surfaces, and especially over other painted surfaces, including murals.
This is a non-drying paint that appears normal while being extremely slippery. It is usually used on drainpipes and ledges to deter burglars and vandals from climbing them, and is found in many public places. When a person attempts to climb objects coated with the paint, it rubs off onto the climber, as well as making it hard for them to climb.
Insulative paint, or insulating paint, reduces the rate of thermal transfer through a surface to which is applied. It consists of any paint with an additive of microspheres that are hollow (vacuum-filled).
FAILURE OF PAINT
The main reasons of paint failure after application on surface are the applicator and improper treatment of surface. Application Defects can be attributed to:
This usually occurs when the dilution of the paint is not done as per manufacturers recommendation. There can be a case of over dilution and under dilution, as well as dilution with the incorrect diluent.
Foreign contaminants added without the manufacturers consent which results in various film defects.
Most commonly due to improper surface treatment before application. Peeling and blistering is also caused due to the inherent moisture/dampness being present in the substrate.
Chalking is the progressive powdering of the paint film on the painted surface. The primary reason for the problem is polymer degradation of the paint matrix due to exposure of UV radiation in sunshine and condensation from dew. The degree of chalking varies as epoxies react quickly while acrylics and polyurethanes can remain unchanged for long periods. The degree of chalking can be assessed according to International Standard ISO 4628 Part 6 or 7 or American Society of Testing and Materials(ASTM) Method D4214 (Standard Test Methods for Evaluating the Degree of Chalking of Exterior Paint Films).
Cracking of paint film is due to the unequal expansion or contraction of paint coats. It usually happens when the coats of the paint are not allowed to cure/dry completely before the next coat is applied. The degree of cracking can be assessed according to International Standard ISO 4628 Part 4 or ASTM Method D661 (Standard Test Method for Evaluating Degree of Cracking of Exterior Paints).
Erosion is very quick chalking. It occurs due to external agents like air, water etc. It can be evaluated using ASTM Method ASTM D662 (Standard Test Method for Evaluating Degree of Erosion of Exterior Paints).
Volatile organic compounds (VOCs) in paint are considered harmful to the environment and especially for people who work with them on a regular basis. Exposure to VOCs has been related to organic solvent syndrome, although this relation has been somewhat controversial.
In many countries, environmental regulations, consumer demand, and advances in technology led to the development of low-VOC and zero-VOC paint and finishes. These new paints are widely available and meet or exceed the old high-VOC products in performance and cost-effectiveness while having significantly less impact on human and environmental health.